Search results for "Confined space"
showing 10 items of 21 documents
Charged supramolecular assemblies of surfactant molecules in gas phase
2015
The aim of this review is to critically analyze recent literature on charged supramolecular assemblies formed by surfactant molecules in gas phase. Apart our specific interest on this research area, the stimuli to undertake the task arise from the widespread theoretical and applicative benefits emerging from a comprehensive view of this topic. In fact, the study of the formation, stability, and physicochemical peculiarities of non-covalent assemblies of surfactant molecules in gas phase allows to unveil interesting aspects such as the role of attractive, repulsive, and steric intermolecular interactions as driving force of supramolecular organization in absence of interactions with surround…
Organic synthesis of high added value molecules with MOF catalysts
2020
Recent examples of organic synthesis of fine chemicals and pharmaceuticals in confined spaces of MOFs are highlighted and compared with silica-based ordered porous solids, such as zeolites or mesoporous (organo)silica. These heterogeneous catalysts offer the possibility of stabilizing the desired transition states and/or intermediates during organic transformations of functional groups and (C-C/C-N) bond forming steps towards the desired functional high added value molecular scaffolds. A short introduction on zeolites, mesoporous silica and metal-organic frameworks is followed by relevant applications in which confined active sites in the pores promote single or multi-step organic synthesis…
Diffusion Control in Single-Site Zinc Reticular Amination Catalysts.
2020
Zn-containing metal-organic frameworks have been used for the first time as heterogeneous catalysts in the amination of C-Cl bonds. The use of extended bis(pyrazolate) linkers can generate highly porous architectures, which favor the diffusion of amines to the confined spaces with respect to other imidazolate frameworks with narrower pore windows. The N4Zn nodes of the Zn-reticular framework show comparable activity to state-of-the-art homogeneous Zn amination catalysts, avoiding the use of basic conditions, precious metals, or other additives. This is combined with long-term activity and stability upon several reaction cycles, without contamination of the reaction product. ispartof: INORGA…
Computational Study on Cesium Azide Trapped in a Cyclopeptidic Tubular Structure
2008
The structures and the electronic properties of host-guest complexes formed by a cyclopeptidic tubular aggregate and the species CsN3, CS2(N-3)(2), and CS2N6 have been investigated by means of density functional theory. Taking advantage of the azide property to act as a bridge ligand between two or more metal cations, it may be possible to trap N-3(-) ions inside a confined space. This could be important for the preparation of polynitrogen molecules N-n. Results show that there are significant attractive interactions between the azide ion and the cavity walls, which make the ion stay inside the inner empty space of the cyclopeptidic aggregate. The confinement of the species CS2(N-3)(2) forc…
Induced Chirality in Confined Space on Halogen Gold Complexes
2015
The solubilization of HAuCl4 in toluene within optically active reverse micelles and lamellar structures formed by (1R,2S)-Dodecyl(2-hydroxy-1-methyl-2-phenylethyl)- dimethylammonium bromide (DMEB) has allowed us to evidence the complex phenomenology accompanying the confinement of Au salt within these nanostructures. Together with a chloride/bromide exchange process occurring in the first coordination sphere of an Au ion, UV−vis and electronic circular dichroism (ECD) spectra reveal the appearance of an induced dichroic signal attributable to Au complexes entrapped in the hydrophilic domain of the DMEB chiral nanostructures. Interestingly, change of the effective oxidation state and coordi…
Bacteria and free-living amoeba in the Lascaux Cave.
2008
3 pages, 1 table, 18 references. The collaboration of the Lascaux restoration team is highly appreciated. We thank Marisa Chelius for valuable comments on the manuscript.
Angle Factors and Projected Area Factors for Comfort Analysis of Subjects in Complex Confined Enclosures: Analytical Relations and Experimental Resul…
2008
This paper addresses an important problem in the evaluation of the thermal comfort of people living or working in the sort of confined spaces typical of current architecture. In the details, a new algorithm is proposed for the evaluation of the angle factors of people within rooms characterized by complex shapes, where the envelope components are not always mutually orthogonal. The algorithm is based on field data obtained by means of an experimental photographic apparatus which allows measurements of projected area factors of seated or standing people in such complex confined environments.
Fine-tuning of the confined space in microporous metal–organic frameworks for efficient mercury removal
2017
Offsetting the impact of human activities on the biogeochemical cycle of mercury has become necessary for a sustainable planet. Herein, we report the development of a water-stable and eco-friendly metal–organic framework, which has the formula {Cu4II[(S,S)-methox]2}·5H2O (1), where methox is bis[(S)-methionine]oxalyl diamide. Its features include narrow functional channels decorated with thioalkyl chains, which are able to capture HgCl2 from aqueous media in an efficient, selective, and rapid manner. The conscious design effort in terms of size, shape, and reactivity of the channels results in extremely efficient immobilization of HgCl2 guest species in a very stable conformation, similar t…
Metal-Organic Frameworks as Chemical Nanoreactors: Synthesis and Stabilization of Catalytically Active Metal Species in Confined Spaces
2020
ConspectusSince the advent of the first metal-organic frameworks (MOFs), we have witnessed an explosion of captivating architectures with exciting physicochemical properties and applications in a wide range of fields. This, in part, can be understood under the light of their rich host-guest chemistry and the possibility to use single-crystal X-ray diffraction (SC-XRD) as a basic characterization tool. Moreover, chemistry on preformed MOFs, applying recent developments in template-directed synthesis and postsynthetic methodologies (PSMs), has shown to be a powerful synthetic tool to (i) tailor MOFs channels of known topology via single-crystal to single-crystal (SC-SC) processes, (ii) impart…
Time evolution of size and polydispersity of an ensemble of nanoparticles growing in the confined space of AOT reversed micelles by computer simulati…
2005
The time dependence of size and polydispersity of an ensemble of nanoparticles growing in the confined space of water-containing AOT reversed micelles has been investigated by computer simulations. It has been found that, in a wide time range, the mean nanoparticle size can be described by power laws whose exponent is critically dependent on the efficiency of the intermicellar material exchange process while the nanoparticle polydispersity increases with time. From the analysis of all the disentangled effects arising from the variation of internal and external parameters provided by simulations, useful suggestions for a better and rationale control of the nanoparticle synthetic procedure ar…